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ISSN Print: 2394-7500, ISSN Online: 2394-5869, CODEN: IJARPF

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International Journal of Applied Research

Vol. 1, Issue 10, Part F (2015)

Kinetics and Mechanistic Study of Ru (III) Catalyst Oxidation of Crotonic Acid by Chloramine-T

Author(s)
Amrita Srivastava, Neelam
Abstract
Catalysed oxidation of Crotonic acid by Ru (III) in acidic medium ofChloramine-T in the presence of Hg(OAc)2 has been investigated. The order with respect to Ru (III)and [Crotonic acid] is one andzero order is found with respect to Chloramine-T.[KCl] shows Positive effect on the reaction rate. The Negligible effect [H+] and ionic strength of medium have been observed. The activation parameters have been computed at different temperatures.Mechanistic steps, consistent with kinetic results, reaction stoichiometry andproduct analysis has been done.
Pages: 380-384  |  635 Views  4 Downloads
How to cite this article:
Amrita Srivastava, Neelam. Kinetics and Mechanistic Study of Ru (III) Catalyst Oxidation of Crotonic Acid by Chloramine-T. International Journal of Applied Research. 2015; 1(10): 380-384.
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