International Journal of Applied Research
Vol. 1, Issue 10, Part F (2015)
Kinetics and Mechanistic Study of Ru (III) Catalyst Oxidation of Crotonic Acid by Chloramine-T
Amrita Srivastava, Neelam
Catalysed oxidation of Crotonic acid by Ru (III) in acidic medium ofChloramine-T in the presence of Hg(OAc)2 has been investigated. The order with respect to Ru (III)and [Crotonic acid] is one andzero order is found with respect to Chloramine-T.[KCl] shows Positive effect on the reaction rate. The Negligible effect [H+] and ionic strength of medium have been observed. The activation parameters have been computed at different temperatures.Mechanistic steps, consistent with kinetic results, reaction stoichiometry andproduct analysis has been done.
How to cite this article:
Amrita Srivastava, Neelam. Kinetics and Mechanistic Study of Ru (III) Catalyst Oxidation of Crotonic Acid by Chloramine-T. Int J Appl Res 2015;1(10):380-384.